Liquid thermoelectric converter with an electromotive force of several hundred millivolts

A coating electrode utilising oxidised graphene particle dispersion exhibits an electromotive force of approximately 300 mV under a 30-degree temperature change.

Advantages

  • By dispersing insulating graphene oxide within the coating electrode material through a novel approach, the electromotive force of liquid thermoelectric devices increased by an order of magnitude compared to conventional methods.
  • Temperature differences between electrodes generate an electromotive force due to changes in the ambient temperature.

Background & Technology

Liquid thermoelectric devices are devices that convert environmental heat into electricity. The researcher had been generating a large thermoelectric voltage using a large-area, low-cost liquid thermoelectric device with a coated electrode containing dispersed graphite particles, but the thermoelectric voltage was only 30-40 mV at a temperature difference of 30 K.

In this study, the researcher generated an electromotive force of approximately 300 mV with a temperature difference of 30 K between electrodes by dispersing insulating graphene oxide in the electrode material. Furthermore, this electromotive force persists even after electrode cooling (e.g., due to daytime heating persisting into nighttime).

Current Stage & Key Data

  • When a 30K temperature difference was applied between the electrodes, the open-circuit voltage (Voc) increased to 292mV (left figure). The maximum output reached 0.40W/m^2 (right figure).
    *The area of the graphene oxide dispersion electrode is 42 mm^2, the electrode spacing is 10 mm, and the electrolyte is a 0.8 M aqueous solution of Fe(ClO₄)₂/Fe(ClO₄)₃.

Partnering Model

  • We are seeking companies interested in exploring patent licensing or joint research opportunities.

Publication(s)

  • The 86th JSAP (The Japan Society of Applied Physics) Autumn Meeting 2025 “Liquid thermoelectric converter with huge electromotive force” (Haruka Yamada et al.)

Patent(s)

  • Patent pending

Principal Investigator

  • Yutaka MORITOMO

(University of Tsukuba, Institute of Pure and Applied Sciences, Professor)

 

 

Project ID:HK-05285

 

Published

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